1，4－二氟四苯基苯的合成、结构与构象

借助电子转移催化反应的方法，用电子给予体１，４－二锂四苯基丁二烯将惰性的三溴氟甲烷活化，并与之发生反应，产物１，４－二氟四苯基苯的结构经ＭＳ、ＮＭＲ和Ｘ射线单晶衍射确证，并以分子力学的方法对其进行了构象分析。     

奇点理论浅引

本文是奇点理论的非正式的介绍。主要内容包括奇点分类与奇点拓扑的基本问题与结果。特别突出了简单奇点的券的性质及其与Ｌｉｅ代数的关系。本文的目的在于引起读者对一分支的兴趣。     

Patterned uniformly orientated silicon nanocrystallite films and efficient field emission characteristics

Patterned uniformly (100)-orientated silicon nanocrystallite (SiNC) films were fabricated based on hydrogen ion implantation technique and typical electrochemical anodic etching method. The surface morphology and microstructure characteristics of the films were characterized by scanning electron microscopy, transmission electron microscopy, X-ray diffraction, and atomic force microscopy. The efficient field emission with low turn-on field of about 3.2 V/μm at current density of 0.1 μA/cm² was obtained. The emission current density from the SiNC films reached 1 mA/cm² under a bias field of about 11 V/μm. The experimental results demonstrate that the SiNC films have great potential applications for flat panel displays.     

Polaron effects on third-harmonic generation in cylindrical quantum-well wires

Polaron effects on third-harmonic generation (THG) in cylindrical quantum wires with a finite confining potential are investigated. The THG coefficient is obtained by using the compact-density-matrix approach and an iterative method, and the numerical results are presented for GaAs/AlAs cylindrical quantum wires. The results show that the THG coefficient is greatly enhanced and the peak shift to the aspect of high energy when considering the influence of electron-phonon interaction.     

Synthesis and Crystal Structure of Di-n-butyltin(IV) Complex with 2-Oxo-propionic Acid (4-Pyridinecarbonyl) Hydrazone

Introduction The studies of diorganotin(IV) complexes are of current interest owing to their wide range of applica-tions such as biocides and homogeneous catalysts in industry.1 In recent years there have been more and more reports on the synthesis, antitumour activities and structural elucidation of various diorganotin(IV) deriva-tives of carboxylic acid.2-5 In particular, people take considerable interest in structural studies of diorgano-tin(IV) complexes of carboxylic acid, because there…     

具有位相型修理的离散时间可修排队系统

本文研究了具有一般独立输入，位相型修理的离散时间可修排队系统，假定服务台对顾客的服务时间和服务台寿命服从几何分布，运用矩阵解析方法我们给出系统嵌入在到达时刻的稳态队长分布和等待时间分布，并证明这些分布均为离散位相型分布．我们也得到在广义服务时间内服务台发生故障次数的分布，证明它服从一个修正的几何分布．我们对离散时间可修排队与连续时间可修排队进行了比较，说明这两种排队系统在一些性能指标方面的区别之处．最后我们通过一些数值例子说明在这类系统中顾客的到达过程、服务时间和服务台的故障率之间的关系．     

123 Phases in CeLa2Cu2MgO8 samples

A tetragonal 123 phase with the composition close to CeLa₂ { Cu ₂ ²⁺ } [Mg²⁺]O₈ (the braces indicate the Cu(2) positions; the brackets indicate the Cu(1) positions) with the parameters a = b = 0.3909(3) nm, c = 1.6591(8) nm was prepared at 860°C under an oxygen atmosphere with an elevated oxygen pressure. When the lanthanum-for-barium substitution was incomplete, the resulting 123 phase had the composition close to CeLa_1.7Ba_0.3{ Cu _1.7 ²⁺ } [Mg]O₈ with the unit cell parameters a = b = 0.3868(3) nm, c = 1.6578(8) nm that contains Cu³⁺ in the Cu(2) positions. The partial substitution of barium for lanthanum (the melting point of barium oxide is almost 500°C lower that of the lanthanum oxide) appreciably facilitated the synthesis: the 123 phase in this sample was more than 90%. The existence of Cu³⁺ in the Cu(2) positions enhanced the electrical conductivity of the sample.